Organic Chemistry MCAT Practice Exam 2025 – 400 Free Practice Questions to Pass the Exam

An NMR peak at 11 ppm typically indicates the presence of a carboxylic acid. In proton NMR (1H NMR) spectroscopy, the chemical shift values provide information about the electronic environment of hydrogen atoms within a molecule.

Carboxylic acids exhibit a characteristic peak that appears downfield (at higher ppm values) due to the strong electronegativity of the carboxyl group (-COOH). The hydrogen atom attached to this group is deshielded because it is involved in hydrogen bonding and interacts with the electron-withdrawing nature of the carbonyl (C=O) oxygen. This deshielding causes the proton to resonate at a higher frequency, corresponding to the 11 ppm range.

In contrast, aldehydes typically resonate around 9-10 ppm, which is lower than carboxylic acids, while aromatic systems have peaks in the range of 6-8 ppm due to the aromatic protons experiencing different electronic environments. Alkyl chains generally produce signals around 0.5-5 ppm, much lower than 11 ppm. Thus, the 11 ppm peak is strongly indicative of a carboxylic acid's hydrogen.